Some stations may have a particular arrangement of gear interacting to make their sound. However commercially available processors have dozens of factory pre-sets for different sounds, and dozens of adjustments that can be applied to pre-sets, or used to create original custom presets. One modern processor can have many different flavors.
Think music. How many different sounds and emotions can be expressed with one musical instrument, such as a piano? Same piano, different artist. Huge difference. Sound is an expression of creativity, skill, available instruments and the performance environment.
Ultimately it is about talent, skill and being in a mental state and physical environment where creativity and performance can happen. Since radio is a business, cost and time devoted to on air sound has to fit into the business plan.
192khz, unless stations are exceeding FCC modulation rule or something is broken or maladjusted, all stations are hitting the same peak level. (unless it is offset as permitted in the rules)
192khz now think about how audio could sound louder to the ear without increasing peak level.