This isn’t an area of expertise for me, but how is it that some frequencies are “used” a lot more than others across the country? For example - 93.9, 101.1, 100.3, 103.5, 104.3, etc are heavily used frequencies, especially in large markets but other mid-sized to smaller ones as well. Meanwhile, a channel like 106.3, 101.3, 100.1, 95.9, etc are a lot less commonly used. Is there anything behind this phenomenon (if it even is one)?
The likely reason for this is that we originally had only three classes of FM stations, A, B, and C, and, much like with AM's, certain frequencies were reserved for certain classes. The classes changed by 1980, which allowed B1, B2, C1, C2, and C3 stations.
Originally, channels 92.1, 92.7, 93.5, 94.3, 95.3, 95.9, 96.7, 97.7, 98.3, 99.3, 100.1, 100.9, 101.7, 102.3, 103.1, 103.9, 104.9, 105.5, 106.3, and 107.1 were reserved for Class A signals, at least on the US mainland. Around 1990, that changed, and we saw a realignment of stations as Class A channels on those frequencies wanted to upgrade, and other stations nearby were forced to move.
Class A signals were generally not desirable in large cities as they didn't cover the entire area. A handful of large cities had some stations on those channels in their suburbs, but you usually didn't see them in the city proper. Most of the stations on those Class A channels that you see in larger cities today were either moved in from the suburbs and upgraded or were forced onto those channels so other stations nearby could upgrade (see KILO 94.3 in Colorado Springs, which was originally on 93.9, for an example of the latter).
So, in larger cities, you had Class B and C stations that couldn't be on those reserved channels. I haven't observed fewer stations on those graveyard FM channels. Smaller towns had fewer radio stations, which meant fewer FM's, but those stations on graveyard channels could be squeezed closer together. Docket 80-90 meant, starting in 1980, more stations got authorized on those channels. Not many markets saw prime real estate handed out thanks to Docket 80-90, though a few did. Most of the Docket 80-90 stations were Class A pea shooters that couldn't do much.