A few of us have witnessed mid-day skywave in Spring and Autumn. Because, for the last 60 years or so most channels are locally blocked, there are not many reports of this in the last half-century.
But in around 1961, at just after noon, EST, in an eastern suburb of Cleveland, I got 4VEH from Cap Haitien, Haiti on 1035 with full readability. Because 1035 is a split frequency, and both KDKA and WBZ were quite a ways away, there was no sideband interference on my HQ-180.
I still wonder why I was even looking for DX in that part of the band at noon. I think it was a teacher's day at school and I was just looking for overlooked stations. I tried from the Bermuda station on 1235, but it was not there, even though it had a much greater salt water path.
The most bizarre was what I witnessed many times in Puerto Rico... at perhaps 3 PM, three hours from sunset, I'd get a variety of stations from places like Libya and Morocco and several of the western sub-Saharan nations on my car radio in San Juan. The path included at least three hours of daylight, making the reception and its extreme clarity quite interesting.