I can find no evidence of WEW being a daytimer prior to 1928. The earliest edition of RADEX on David's site, from October 1926, shows WEW as one of three stations still operating on the old 360 meter channel where broadcast radio began. It's shown with 1000 watts on 360 meters (833 kc), with no indication of any daytime-only restriction. The only other stations still on the channel were WPAP/WQAO in the New York City area.
By 1928, just before General Order 40 took effect, WEW was on 850 kc, which appears to have been the rough equivalent of a "regional" channel in the days before those designations were used. It had 1000 watts, with no indication of daytime-only operation, with three other (fairly prominent) stations on the channel: KLZ Denver, WWJ Detroit and KYA San Francisco.
General Order 40 didn't quite get all of those stations to their final places, but it got them close: KLZ landed on 560, where it's been ever since. KYA landed on 1220, a regional channel, and would shift once more, to 1230, before ending up on 1260 where it remained. WWJ actually got a clear channel out of the deal: it went to 820, and had the channel to itself, but that didn't last long before WHAS took the 820 clear and WWJ went to 920, which morphed to 950 in NARBA.
And WEW? General Order 40 landed it on 760 kc, where its only co-channel neighbor was WJZ in New York. The 1928 RADEX showing the General Order 40 changes doesn't identify WEW's operation on 760 as a daytime-only license, but I believe it had to have been the case, if not right away in 1928 then pretty quickly thereafter, since WJZ on 760 had the channel completely clear at night.
Indeed, even after the NARBA shift to 770, the channel-sharing that was put in place by General Order 40 remains in place today: WEW as a 1000-watt daytimer, WJZ (WABC) as the I-A clear.
(Yes, I'm well aware of the long, bitter fight between WABC and KOB for that I-A status, but that's irrelevant to WEW!)