Big WISE in Asheville.Programmed by the late, great Bob Kaghan (the guy who put John Boy and Billy together, BTW), Then later by Mark St. John, who went on to program WAVA in Washington in the 80's and by Ray Wildman Williams by the end of the decade.
WOOW in Greenville,which at one time was the home of Jack Daniel, ,a long time Charlotte legend, Henry Hinton, who later went to WGH in Norfolk and is now an owner in Eastern Carolina. Marc Mitchell who later worked in Boston and Detroit. The station was programmed by Carl Davis who made his fame in the engineering world.
WSFL in New Bern which I think was one of the first FM Top 40's NC.
WXQR in Jacksonville, which started out as a Top 40/Progressive Rock hybrid.
WQDR in Raleigh, the station that brought FM Rock radio to critical mass, here in NC.
There are so many more. Of course, we can't forget WAYS, WBT, WKIX, WFLB in Fayette-nam, WAIR and WTOB in Winston