These were the only two stations operating in Arizona at the time. From the 3/16/53 Tucson Daily Citizen:
Monday, March 16, 1953
Channel 13 - KOPO-TV Tucson
4:00 Visiting with Virginia
4:50 Telenews
5:00 Rhythm Time
5:15 Telecomica
5:30 Trail Blazers
5:55 Weather
6:00 Graham French
6:30 Telenews
6:45 Sports with Perlin
7:00 KOPO Playhouse
7:30 Files of Jeffrey Jones
8:00 Bishop Sheen
8:30 Life Begins at 80
9:00 Wrestling
10:00 Telenews
10:10 This Is Life
10:15 File Facts
10:20 Late Movie
Channel 5 - KPHO-TV Phoenix
11:30 Movie Time
12:30 Music After Show
1:00 Big Payoff
1:30 Ken's Kerousal
1:45 Welcome Travelers
2:00 Music With a Smile
2:30 Strike It Rich
3:00 Cook's Corner
4:00 Popular Astronomy
4:30 Love of Life
4:45 Search for Tomorrow
5:00 Luke Field Presents
5:30 What's Your Trouble
5:45 Sketchbook Cartoons
6:00 Those Two
6:15 News
6:30 Purity Playhouse
7:00 Desert Denizens
7:30 Range Rider
9:00 Death Valley Days
9:30 "300" Playhouse
10:00 World Report
10:30 Martin Kane
11:00 Mr. and Mrs. North
11:30 Movie Time
Tuesday, March 17, 1953
Channel 13 - KOPO-TV Tucson
4:00 Visiting with Virginia
4:50 Telenews
5:00 Rhythm Time
5:15 Telecomica
5:20 Bar Nothing Ranch
5:50 Sewing - Weather
6:00 Selected Shorts
6:30 Telenews
6:45 Sports with Perlin
7:00 Dick Tracy
7:30 TV Theater
8:00 Boston Blackie
8:30 Dean Armstrong
9:00 Wrestling
10:00 Telenews
10:20 Late Movie
Channel 5 - KPHO-TV Phoenix
11:30 Movie Time
12:30 Music After Show
1:00 Big Payoff
1:30 Ken's Kerousal
1:45 Welcome Travelers
2:00 Kate Smith
2:30 Garry Moore
3:00 Art In Your Life
3:30 Cook's Corner
4:30 Love of Life
4:45 Search for Tomorrow
5:00 Scouting In Action
5:30 Dinah Shore
5:45 Sketchbook Cartoons
6:00 Industry On Parade
6:15 News
6:30 TV Spotlight
7:00 Hopalong Cassidy
7:30 Liberace
8:00 You Asked for It
8:30 Dangerous Assignment
9:00 Two for the Money
9:30 Washington Spotlight
9:45 M.D.'s Notebook
10:00 Playhouse of Stars
10:30 Red Skelton
11:30 Movie Time
Monday, March 16, 1953
Channel 13 - KOPO-TV Tucson
4:00 Visiting with Virginia
4:50 Telenews
5:00 Rhythm Time
5:15 Telecomica
5:30 Trail Blazers
5:55 Weather
6:00 Graham French
6:30 Telenews
6:45 Sports with Perlin
7:00 KOPO Playhouse
7:30 Files of Jeffrey Jones
8:00 Bishop Sheen
8:30 Life Begins at 80
9:00 Wrestling
10:00 Telenews
10:10 This Is Life
10:15 File Facts
10:20 Late Movie
Channel 5 - KPHO-TV Phoenix
11:30 Movie Time
12:30 Music After Show
1:00 Big Payoff
1:30 Ken's Kerousal
1:45 Welcome Travelers
2:00 Music With a Smile
2:30 Strike It Rich
3:00 Cook's Corner
4:00 Popular Astronomy
4:30 Love of Life
4:45 Search for Tomorrow
5:00 Luke Field Presents
5:30 What's Your Trouble
5:45 Sketchbook Cartoons
6:00 Those Two
6:15 News
6:30 Purity Playhouse
7:00 Desert Denizens
7:30 Range Rider
9:00 Death Valley Days
9:30 "300" Playhouse
10:00 World Report
10:30 Martin Kane
11:00 Mr. and Mrs. North
11:30 Movie Time
Tuesday, March 17, 1953
Channel 13 - KOPO-TV Tucson
4:00 Visiting with Virginia
4:50 Telenews
5:00 Rhythm Time
5:15 Telecomica
5:20 Bar Nothing Ranch
5:50 Sewing - Weather
6:00 Selected Shorts
6:30 Telenews
6:45 Sports with Perlin
7:00 Dick Tracy
7:30 TV Theater
8:00 Boston Blackie
8:30 Dean Armstrong
9:00 Wrestling
10:00 Telenews
10:20 Late Movie
Channel 5 - KPHO-TV Phoenix
11:30 Movie Time
12:30 Music After Show
1:00 Big Payoff
1:30 Ken's Kerousal
1:45 Welcome Travelers
2:00 Kate Smith
2:30 Garry Moore
3:00 Art In Your Life
3:30 Cook's Corner
4:30 Love of Life
4:45 Search for Tomorrow
5:00 Scouting In Action
5:30 Dinah Shore
5:45 Sketchbook Cartoons
6:00 Industry On Parade
6:15 News
6:30 TV Spotlight
7:00 Hopalong Cassidy
7:30 Liberace
8:00 You Asked for It
8:30 Dangerous Assignment
9:00 Two for the Money
9:30 Washington Spotlight
9:45 M.D.'s Notebook
10:00 Playhouse of Stars
10:30 Red Skelton
11:30 Movie Time