Well, MC, there is a lot to be said here. What you were getting was reflection (OK,
refraction, to be exact, but that's a bit esoteric) off the E-layer of the ionosphere, which happens sporadically,
usually in the Summer. This phenomenon is suitably called, "sporadic-E." The higher the frequency, the rarer the event.
Getting a path from Pittsburgh to Jackson, MS is very typical of this mode. Paths from -- say -- 700 to 1100 miles are normal here. These events are not really predictable, but follow clear patterns.
Wikipedia has a brief article on this:
http://en.wikipedia.org/wiki/Sporadic_E For more in-depth information, the article cited at the bottom is a great read.
There are hobbyists who really get off on this, looking for TV and/or FM from far away. They have a club; here's the website:
http://www.wtfda.org/ I am a ham, and spend most of my operating time on VHF (50 MHz & 144 MHz); sporadic-E is what I spend much of my Summer waiting for.
Oh, and to answer the original poster, yes... I did see some rather extreme DX that day. Again, I was hanging out on the 144 MHz ham band. And, I had about 20 minutes of an opening from here (Memphis) to the Northeast. This is a treat, as 144 MHz doesn't see sporadic-E very often at all.
Enjoy,
DE