Radio waves can propagate over the horizon when the lower atmosphere of the earth bends, scatters, and/or reflects the electromagnetic fields. These effects are collectively known as tropospheric propagation, or tropo for short. Tropospheric propagation can affect wireless communications, sometimes enhancing the usable range, but also compounding interference problems.
A less common, but often dramatic, form of tropo is called ducting or duct effect. This occurs when there is a defined, horizontal boundary between air masses having different densities. When a cool air mass is overlain by a warm air mass, as is the case along and near warm fronts and cold fronts, radio waves at VHF and UHF are reflected at the boundary if they strike it at a near-grazing angle from beneath (within the cooler air mass). Because radio waves are also reflected from the earth's surface, the result can be efficient propagation for hundreds or, in some cases, upwards of 1,000 miles, as the waves alternately bounce off the frontal boundary and the surface. Ducting can allow long-distance radio reception in the frequency-modulation (FM) broadcast band between 88 and 108 MHz. It can also affect the lower VHF television channels if receiving antennas (rather than cable networks) are used.
This is most likely what caused 103.3 to be "covered up" by the distant station.
For the complete story on Scatter, Ducting, and other means of signals reaching beyond their normal distances, check out this link.
http://www.mmmonvhf.de/tr.php
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